向丽

向丽

向丽，女，汉族，博士，副教授，硕士生导师

Email: xiangli@cqnu.edu.cn

主要研究方向：

金属有机化学

教育经历：

2010.08 – 2014.12 香港中文大学化学系，有机化学，博士，（导师：谢作伟教授）

2006.09 – 2009.07 北京师范大学化学学院，有机化学，硕士，（导师：自国甫教授）

2002.09 – 2006.07 北京师范大学化学学院，本科

工作经历：

2019.09 – 至今 重庆师范大学

2017.05 – 2019.09 中国科学院上海有机化学研究所，金属有机国家重点实验室，副研究员

2016.02 – 2017.05 中国科学院上海有机化学研究所，金属有机国家重点实验室，助理研究员

2015.01 – 2016.01 香港中文大学化学系，研究助理

2009.12 – 2010.07 中国科学院上海有机化学研究所，金属有机国家重点实验室，研究助理

获奖及荣誉：

香港中文大学Wong Siew Hkoon 夫人奖学金，2010

香港特区政府奖学金，2010–2013

承担的主要科研项目：

主持国家自然科学基金青年科学基金项目1项（2017.01-2019.12），国家自然科学基金面上项目1项（2021.01-2024.12），重庆市教委科技项目1项（2022.01-2024.12）。

代表性论文：

1. Wen, Q. Q.; Feng B.; Xiang L.;* Leng, X. B.; Chen, Y. F.* Divalent Ytterbium Hydrido Complex Supported by a β-Diketiminato-Based Tetradentate Ligand: Synthesis, Structure and Reactivity. Inorg. Chem. 2021, 60, 13913−13919.

2. Liu, X. J.; Wen, Q. Q.; Xiang, L.;* Leng, X. B.; Chen, Y. F.* Samarium(II) Monoalkyl Complex Supported by a β-Diketiminato Based Tetradentate Ligand: Synthesis, Structure and Catalytic Hydrosilylation of Internal Alkynes. Chem. Eur. J. 2020, 26, 5494−5499.

3. Liu, X. J.; Xiang, L.;* Louyriac, E.; Maron, L.;* Leng, X. B.; Chen, Y. F.* Divalent Ytterbium Complex-Catalyzed Homo- and Cross-Coupling of Primary Arylsilanes. J. Am. Chem. Soc. 2019, 141, 138−142.

4. Mao, W. Q.; Wang, Y. Y.; Xiang, L.;* Peng, Q.;* Leng, X. B.; Chen, Y. F*. Scandium Phosphonioketene: Synthesis, Bonding and Reactivity. Chem. Eur. J. 2019, 25, 10304−10308.

5. Wang, C.; Mao, W. Q.; Xiang, L.;* Yang, Y.; Fang, J.; Maron, L.;* Leng, X. B.; Chen, Y. F.* Monomeric Rare-Earth Metal Silyl-Thiophosphinoyl-Alkylidene Complexes: Synthesis, Structure, and Reactivity. Chem. Eur. J. 2018, 24, 13903−13917.

6. Feng, G. Q.; Du, C. Y.; Xiang, L.;*, del Rosal, I.; Li, G. Y.; Leng, X. B.; Chen, E. Y.-X.;* Maron, L.;* Chen, Y. F.* Side Arm Twist on Zn-Catalyzed Hydrosilylative Reduction of CO₂ to Formate and Methanol Equivalents with High Selectivity and Activity. ACS Catal. 2018, 8, 4710−4718.

7. Wang, C. H.; Xiang, L.;* Leng, X. B.; Chen, Y. F.* Rare-Earth Metal Hydrides Supported by Silicon-Bridged Boratabenzene Fluorenyl Ligands: Synthesis, Structure and Reactivity. Dalton Trans. 2017, 46, 1218−1227.

8. Xiang, L.; Xie, Z. W.* Reaction of [η¹:η⁵-(R₂NCH₂CH₂)C₂B₉H₁₀]TaMe₃ with Isonitriles: Effects of Nitrogen Substituents on Product Formation. Organometallics 2016, 35, 1430−1439.

9. Xiang, L.; Xie, Z. W.* Tantallacarborane Mediated Consecutive C−C and C−N Coupling Reactions of Alkyl Isonitriles: a Facile Route to N-Containing Heterocycles. Organometallics 2016, 35, 233−241.

10. Xiang, L.; Xie, Z. W.* Conversion of (η⁵-C₂B₉H₁₀R)TaX₃ (X = Me, NMe₂) to (η⁶-C₂B₉H₁₀R)TaX’ (X’ = NMe₂, azaallyl) in the Absence of a Reducing Agent: Synthesis and Structure of Tantallacarboranes Incorporating an arachno-η⁶-C₂B₉^4- Ligand. Chem. Commun. 2014, 50, 8249−8252.

11. Xiang, L.; Mashima, K.; Xie, Z. W.* Reaction of [η¹:η⁵-(Me₂NCH₂CH₂)C₂B₉H₁₀]TaMe₃ with Aryl Isonitriles: Tantallacarborane-Mediated Facile Cleavage of C−N Multiple Bonds. Chem. Commun. 2013, 49, 9039−9041.

12. Xiang, L.; Xiao, J.; Deng, L.* Synthesis, Structure and Reactivity of Organo-Iron(II) Complexes with N-Heterocyclic Carbene Ligation. Organometallics 2011, 30, 2018−2025.

13. Zi, G. F.*; Xiang, L.; Song, H. B. Enantioselective Hydroamination/Cyclization Catalyzed by Organolanthanide Amides Derived from a New Chiral Ligand, (S)-2-(Pyrrol-2-ylmethyleneamino)-2’-dimethylamino-1,1’-binaphthyl. Organometallics 2008, 27, 1242−1246.

14. Xiang, L.; Wang, Q. W.; Song, H. B.; Zi, G. F.* Synthesis, Structural Characterization, and Reactivity of Organolanthanides Derived from a New Chiral Ligand, (R)-Bis(pyrrol-2-ylmethyleneamino)-1,1’-binaphthyl. Organometallics 2007, 26, 5323−5329.